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How Silicone-Based DPC Injection Works in Masonry

What Actually Happens Inside the Wall

This page explains the chemical and physical mechanisms by which silicone-based DPC injection fluids operate within masonry. It focuses on what occurs inside the pore structure after injection and why correct distribution and saturation are critical.


It is intended as a technical reference for contractors and specifiers, not a marketing overview.

DPC Injection Chemistry

Masonry as a Porous System

Masonry materials such as brick, stone, and mortar contain a network of capillaries and pores. Rising damp occurs when water migrates upward through this network due to capillary action.

Chemical DPC injection does not block these pores. Instead, it modifies how water interacts with the pore surfaces.

Silane and Siloxane Chemistry (Overview)

Silicone-based DPC systems typically contain alkoxysilanes and siloxanes.

Once injected into masonry, these compounds undergo two key reactions:

  1. Hydrolysis – reaction with moisture within the masonry
  2. Condensation – bonding to mineral substrates

 

These reactions occur naturally within the wall after injection.

Chemical Bonding to the Substrate

Masonry minerals contain surface hydroxyl (–OH) groups.

During condensation:

Silane molecules chemically bond to these hydroxyl groups

Covalent bonds form between the silicone compound and the masonry surface

A durable, chemically anchored treatment is created within the pore walls

This is a chemical bond, not a surface coating.

Formation of a Hydrophobic Pore Lining

Once bonded:

The pore walls become hydrophobic

The pore structure remains open to vapour movement

Liquid water is no longer able to wet the pore surfaces

The treated zone functions as an internal damp-proof course.

Effect on Water Behaviour

The injected silicone system does not convert water or block moisture mechanically.

Instead, it alters water behaviour by:

  • Increasing the contact angle of water within pores
  • Preventing capillary rise
  • Allowing gravity drainage and evaporation to occur

 

Water vapour can still pass through the wall.

Barrier Formation Within the Wall

When correctly dosed and distributed:

  • Individual treated pores overlap laterally
  • A continuous hydrophobic zone forms
  • This zone interrupts upward moisture movement across the wall thickness

 

Continuity depends on correct drilling, spacing, and saturation.

Role of Saturation

Chemical bonding occurs only where the fluid reaches.

Insufficient saturation leads to:

  • Untreated pore pathways
  • Discontinuous barriers
  • Apparent failure despite correct chemistry

 

Correct volume and distribution are critical.

Salt Interaction

Hygroscopic salts do not prevent chemical bonding, but they:

  • Retain moisture above the DPC
  • Can continue attracting water vapour after injection

 

Salt-affected plaster and mortar should be removed where required to avoid misleading post-treatment symptoms.

What This System Does Not Do

  • It does not seal the wall
  • It does not trap moisture
  • It does not rely on membrane insertion
  • It does not require the wall to dry before bonding occurs

Key Takeaway

Silicone-based DPC injection works by chemically modifying the internal pore surfaces of masonry, creating a vapour-permeable, water-repellent zone that interrupts capillary moisture rise when correctly installed.

Explore the Silonexx chemical DPC injection fluid specification and supply options.